Found 10497 results, showing the newest relevant preprints. Sort by relevancy only.Update me on new preprints

Novel Protective Group Synthesis of Androgen Receptor Modulators with Steroidal and Nonsteroidal Scaffolds

Selective androgen receptor modulators (SARMs) are supposed to diminish the adverse androgenic AAS effects while maximizing anabolic effects. Expand abstract.
18314 days ago
4/10 relevant
chemRxiv

Substituent Effects on the Thermal Decomposition of Phosphate Esters on Ferrous Surfaces

The results highlight surface and substituent effects on the thermal decomposition of phosphate esters which should be helpful for the design of new molecules with improved performance. Expand abstract.
18314 days ago
5/10 relevant
chemRxiv

Sunlight-Driven Photocatalytic Hydrogen Production from Water Using Metal-Doped Strontium Titanate Perovskite

Furthermore, the effects of the amount of catalyst, the proportion of sacrificial agent and pH were studied for the SrTiO3:Rh (1 mol%) along with studying its activity with seawater. Expand abstract.
18314 days ago
4/10 relevant
chemRxiv

Discovery of an Unexpected Similarity in Ligand Binding Between BRD4 and PPARγ

Such a dual-BRD4-PPARγ-modulator could show synergistic effects with a higher efficacy or delayed resistance development in, for example, cancer therapy. Expand abstract.
18314 days ago
4/10 relevant
chemRxiv

Stereoelectronic Effects Impact Glycan Recognition

Thus, our data highlight a role for stereoelectronic effects in dictating the specificity of glycan recognition by proteins. Expand abstract.
18314 days ago
7/10 relevant
chemRxiv

Effect of an Al(III) Complex on the Regio- and Stereoisomeric Formation of Bicyclic Organic Carbonates

Control experiments combined with DFT calculations provide a rationale for the distinct catalytic manifolds observed in the presence and absence of the Al(III) complex. Expand abstract.
18314 days ago
4/10 relevant
chemRxiv

Bond-Length Distributions for Ions Bonded to Oxygen: Results for the Transition Metals and Quantification of the Factors Underlying Bond-Length Variation in Inorganic Solids

However, we sometimes observe multiple bonds to form as a result of electronic effects (e.g. the pseudo Jahn-Teller effect); resolution of the origins of multiple-bond formation follows calculation of the Δ𝑡𝑜𝑝𝑜𝑙 and Δ𝑐𝑟𝑦𝑠𝑡 indices on a structure-by-structure basis. Expand abstract.
18314 days ago
6/10 relevant
chemRxiv

On the Crystal Chemistry of Inorganic Nitrides: Crystal-Chemical Parameters and Opportunities in the Exploration of Their Compositional Space

We find that many mechanisms of bond-length variation ubiquitous to oxide and oxysalt compounds (e.g., lone-pair stereoactivity, the Jahn-Teller and pseudo Jahn-Teller effects) are similarly pervasive in inorganic nitrides, and are occasionally observed to result in greater distortion magnitude than their oxide counterparts. Expand abstract.
18314 days ago
4/10 relevant
chemRxiv

A Simple Method for Incorporating Polarization Effects in Solvation Free Energy Calculations Using Fixed-Charge Force Fields

We note that APolQ can in principle be applied to any pure or mixed solvent. Expand abstract.
18314 days ago
5/10 relevant
chemRxiv

Chemical Vapor Deposition of Sp2-Boron Nitride on Si(111) Substrates from Triethylboron and Ammonia: Effect of Surface Treatments

We accomplish this condition by a nitridation procedure in a deposition chamber where BxC had previously been deposited at high temperature, but where the synthesis route needs to be further developed for a better process control. Expand abstract.
18314 days ago
4/10 relevant
chemRxiv